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#61
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I ask out of ignorance
Mayayana wrote:
"Mark Lloyd" wrote | Interesting. I didn't know about the flammability. | But gas stoves were used in suicide without the | flame on. (One of my grandmothers did that. The | gas never lit. In other words, she was killing herself | with gas, not CO. My grandfather discovered her with | her head in the oven. Even natural gas needs a high | concentration to ignite.) | Also, natural gas is not poisonous. The problem with a gas-filled space | is lack of oxygen. | Grandma must have timed it well to be gone just around the time Grandpa came home. He was a heavy cigar smoker. I always wondered whether she understood the risk she was imposing on others. But she had late-stage breast cancer and in those days there was nothing to be done. I assume she *thought* she was saving everyone a lot of trouble. Maybe natural gas is an easy way to pass out without struggle? I don't know. I think it's the urban legend nature of sticking your head in the oven, that would do it. Maybe on The Honeymooners there would be a reference to "taking the gas pipe". and that would popularize the notion. ******* https://www.healthline.com/health/gas-leak-symptoms "Extreme or high levels of exposure may also cause unconsciousness or death." Which I suppose, is hypoxia. Paul |
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#62
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I ask out of ignorance PS
On Sat, 24 Nov 2018 10:12:56 -0500, "Mayayana"
wrote: "Wolf K" wrote | It's surprising but true that newspapers are sometimes taken in by these | tales, especially if the purveyor has added plausible names and dates, etc. | Before you embarass yourself further with your glib cynicism and even more glib dismissals of others as being liars or idiots, do a search on this: Albert Senzatimore carbon monoxide Numerous newspapers reported the story. The American Bar Association also did a piece because there was a somewhat unusual lawsuit involved. http://www.abajournal.com/news/artic...onoxide_death/ Oddly, so far I haven't found a story about homes being destroyed by exploding CO gas. Maybe you or Eric could post a link to that one. Was it the case of Elmer Fudd vs Daffy Duck, by any chance? Carbon Monoxide poisoning is usually slow. If it's fast it normally gives rise to physical symptoms e.g. headache, ataxia, chest pains etc. A very high level of CO is required to kill within minutes in which case the concentration is dangerously close to the lower explosive limit, 12.5% from memory. I have no doubt that those guys died from CO poisoning but not quite as described. -- Regards, Eric Stevens |
#63
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I ask out of ignorance
On Sat, 24 Nov 2018 11:39:06 -0600, Mark Lloyd
wrote: Also, natural gas is not poisonous. The problem with a gas-filled space is lack of oxygen. Also, natural gas doesn't smell. In the UK there is something added to make it smell. Steve -- http://www.npsnn.com |
#64
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I ask out of ignorance
On Sun, 25 Nov 2018 10:06:38 +0000, Stephen Wolstenholme
wrote: On Sat, 24 Nov 2018 11:39:06 -0600, Mark Lloyd wrote: Also, natural gas is not poisonous. The problem with a gas-filled space is lack of oxygen. Also, natural gas doesn't smell. In the UK there is something added to make it smell. Thiols. They contain sulphur and smell as though they contain sulphur. Many things containing sulphur smell similar to things that contain sulphur. Eggy, yolky smell. https://en.wikipedia.org/wiki/Thiol https://en.wikipedia.org/wiki/Natural_gas#Added_odor Natural gas is quite dangerous. Knowing when it's around is potentially a very good idea. Note: lighting a scented candle to cover the smell of a leak is often considered to be ill-advised and potentially harmful. Mand. Steve |
#65
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I ask out of ignorance PS
On Sun, 25 Nov 2018 12:24:15 +1300, Eric Stevens
wrote: A very high level of CO is required to kill within minutes in which case the concentration is dangerously close to the lower explosive limit, 12.5% from memory. Here is a table showing the effect of different levels of CO: Concentration Symptoms 35 ppm (0.0035%) Headache and dizziness within six to eight hours of constant exposure 100 ppm (0.01%) Slight headache in two to three hours 200 ppm (0.02%) Slight headache within two to three hours; loss of judgment 400 ppm (0.04%) Frontal headache within one to two hours 800 ppm (0.08%) Dizziness, nausea, and convulsions within 45 min; insensible within 2 hours 1,600 ppm (0.16%) Headache, increased heart rate, dizziness, and nausea within 20 min; death in less than 2 hours 3,200 ppm (0.32%) Headache, dizziness and nausea in five to ten minutes. Death within 30 minutes. 6,400 ppm (0.64%) Headache and dizziness in one to two minutes. Convulsions, respiratory arrest, and death in less than 20 minutes. 12,800 ppm (1.28%) Unconsciousness after 2–3 breaths. Death in less than three minutes. So it takes only 1,28 %CO to kill in less than 3 minutes. -- Jesper Kaas - |
#66
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I ask out of ignorance PS
Wolf K wrote:
On 2018-11-25 09:55, Jesper Kaas wrote: On Sun, 25 Nov 2018 12:24:15 +1300, Eric Stevens wrote: A very high level of CO is required to kill within minutes in which case the concentration is dangerously close to the lower explosive limit, 12.5% from memory. Here is a table showing the effect of different levels of CO: Concentration Symptoms 35 ppm (0.0035%) Headache and dizziness within six to eight hours of constant exposure 100 ppm (0.01%) Slight headache in two to three hours 200 ppm (0.02%) Slight headache within two to three hours; loss of judgment 400 ppm (0.04%) Frontal headache within one to two hours 800 ppm (0.08%) Dizziness, nausea, and convulsions within 45 min; insensible within 2 hours 1,600 ppm (0.16%) Headache, increased heart rate, dizziness, and nausea within 20 min; death in less than 2 hours 3,200 ppm (0.32%) Headache, dizziness and nausea in five to ten minutes. Death within 30 minutes. 6,400 ppm (0.64%) Headache and dizziness in one to two minutes. Convulsions, respiratory arrest, and death in less than 20 minutes. 12,800 ppm (1.28%) Unconsciousness after 2–3 breaths. Death in less than three minutes. So it takes only 1,28 %CO to kill in less than 3 minutes. Well below flammable/explosive level, then. Some interesting breadcrumbs here. https://coldcraft.com/los-gatos-and-...-co-poisoning/ There's a picture of the furnace on that web page. It looks like an older furnace, not a high efficiency one. It looks similar to the design of my old furnace, with convection as the source of airflow. Now, the interesting part, is the reaction of the officers who entered the residence. "Two Truckee Police Department officers found the men dead inside a home at 13600 Weisshorn Avenue in Tahoe Donner on Oct. 26. The officers soon began suffering respiratory issues and left the residence, which had "very high" levels of carbon monoxide, according to police. " Which means there was enough non-CO materials in the air to trigger lung problems for the officers. Just like with my furnace, which at 3ppm had me coughing from the combustion products in the air. You could smell that exhaust was entering the premises. Why didn't the victims recognize the same thing ? Even if one of the victims had impaired olfactory sense, you'd think the second would recognize something wasn't right. The combustion products will have you coughing - it's not something you can exactly ignore. Paul |
#67
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I ask out of ignorance PS
On Sun, 25 Nov 2018 12:42:34 -0500, Paul wrote:
Wolf K wrote: On 2018-11-25 09:55, Jesper Kaas wrote: On Sun, 25 Nov 2018 12:24:15 +1300, Eric Stevens wrote: A very high level of CO is required to kill within minutes in which case the concentration is dangerously close to the lower explosive limit, 12.5% from memory. Here is a table showing the effect of different levels of CO: Concentration Symptoms 35 ppm (0.0035%) Headache and dizziness within six to eight hours of constant exposure 100 ppm (0.01%) Slight headache in two to three hours 200 ppm (0.02%) Slight headache within two to three hours; loss of judgment 400 ppm (0.04%) Frontal headache within one to two hours 800 ppm (0.08%) Dizziness, nausea, and convulsions within 45 min; insensible within 2 hours 1,600 ppm (0.16%) Headache, increased heart rate, dizziness, and nausea within 20 min; death in less than 2 hours 3,200 ppm (0.32%) Headache, dizziness and nausea in five to ten minutes. Death within 30 minutes. 6,400 ppm (0.64%) Headache and dizziness in one to two minutes. Convulsions, respiratory arrest, and death in less than 20 minutes. 12,800 ppm (1.28%) Unconsciousness after 2–3 breaths. Death in less than three minutes. So it takes only 1,28 %CO to kill in less than 3 minutes. Well below flammable/explosive level, then. Some interesting breadcrumbs here. https://coldcraft.com/los-gatos-and-...-co-poisoning/ There's a picture of the furnace on that web page. It looks like an older furnace, not a high efficiency one. It looks similar to the design of my old furnace, with convection as the source of airflow. Now, the interesting part, is the reaction of the officers who entered the residence. "Two Truckee Police Department officers found the men dead inside a home at 13600 Weisshorn Avenue in Tahoe Donner on Oct. 26. The officers soon began suffering respiratory issues and left the residence, which had "very high" levels of carbon monoxide, according to police. " Which means there was enough non-CO materials in the air to trigger lung problems for the officers. Just like with my furnace, which at 3ppm had me coughing from the combustion products in the air. You could smell that exhaust was entering the premises. Why didn't the victims recognize the same thing ? Even if one of the victims had impaired olfactory sense, you'd think the second would recognize something wasn't right. The combustion products will have you coughing - it's not something you can exactly ignore. Why didn't the victims recognize the same thing? Because CO is colorless, odorless, and tasteless. I think you're confusing exhaust from your old furnace with CO. The exhaust most likely _contained_ a small amount of CO, but that's about it. The majority was smoke of some kind. CO won't have you coughing or smelling anything unusual. Humans can't see, smell, or taste CO. That's why CO detectors were developed. https://www.cdc.gov/co/faqs.htm What is Carbon Monoxide? Carbon monoxide, or “CO,” is an odorless, colorless gas that can kill you. Back in the 90's, a friend of mine was feeling sick in the evenings when she was home and fine during the day when she was at work. Likewise for her son - sick in the evenings and fine at school. After a few days of that, her furnace failed and she brought in a repairman. He discovered that the flue was plugged by a squirrel nest and the furnace exhaust had been venting into the basement. She and her son were lucky they were able to wake up each morning while that was going on. Neither of them smelled anything unusual. If she'd had a CO detector, I'm sure it would have gone nuts. |
#68
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I ask out of ignorance
On 11/25/18 4:06 AM, Stephen Wolstenholme wrote:
[snip] Also, natural gas doesn't smell. In the UK there is something added to make it smell. Steve I live near New London, Texas. I lost a relative in the school explosion of 1937. This in in the oilfield, and the school was getting free gas. The lack of smell led to a large natural gas accumulation in the basement. From what I heard, this explosion was one reason for introducing the smell. -- 30 days until the winter celebration (Tue Dec 25, 2018 12:00:00 AM for 1 day). Mark Lloyd http://notstupid.us/ "The Christian religion not only was at first attended with miracles, but even at this day cannot be believed by any reasonable person without one." -- David Hume |
#69
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I ask out of ignorance PS
"Paul" wrote
| The officers soon began suffering respiratory issues and | left the residence, which had "very high" levels of | carbon monoxide, according to police. | " | | Which means there was enough non-CO materials in the air | to trigger lung problems for the officers. | | Just like with my furnace, which at 3ppm had me coughing | from the combustion products in the air. You could smell | that exhaust was entering the premises. | | Why didn't the victims recognize the same thing ? It doesn't say the cops smelled something. I'm guessing that even if the two men smelled something, they wouldn't have left. What would you do? Probably head for the cellar to see what's wrong, right? Not realizing that you were going to pass out before you got that far. It would never occur to me to think, "Oh, something seems to be burning. I'd better run out the door before I die!" But with the cops, they already see two dead men and furnace repair is not part of their job. .... Leastways that's my guess. At this point we're just making it up, dressing a meager skeleton of actual facts with speculation. I'm happy just to confirm that controlling home appliances with a cellphone remotely is a fatal addiction. |
#70
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I ask out of ignorance
Stephen Wolstenholme wrote:
On Sat, 24 Nov 2018 11:39:06 -0600, Mark Lloyd wrote: Also, natural gas is not poisonous. The problem with a gas-filled space is lack of oxygen. Also, natural gas doesn't smell. In the UK there is something added to make it smell. Smelly agent is added in the USA also. -- Tim Slattery tim at risingdove dot com |
#71
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I ask out of ignorance
"Tim Slattery" wrote in message
... Stephen Wolstenholme wrote: On Sat, 24 Nov 2018 11:39:06 -0600, Mark Lloyd wrote: Also, natural gas is not poisonous. The problem with a gas-filled space is lack of oxygen. Also, natural gas doesn't smell. In the UK there is something added to make it smell. Smelly agent is added in the USA also. Mercaptans are the stenching agent that are added. Also present in asparagus and excreted, by some people, in their urine for several hours afterwards - I speak as a sufferer of "Asparagus Wee". I remember when I was working in a chemistry lab during my year off before university. One of the chemicals we used (I forget what it was) was the component that gives vomit its repulsive smell. We worked on it *only* in the fume cupboard. One day the Big Boss was bringing round an important guest, and he took the official party through our lab. One of my colleagues was slightly flustered to see all these important guests, and accidentally knocked over the little bottle of Essence of Puke. Despite the inward draught of the fume cupboard, enough of the vapour escaped to make a very noticeable pong. The Big Boss looked very concerned and whispered to my manager "Is everybody... er, OK. Or has someone just been... ill". Ah, I've just googled. Butyric acid is the stuff that make puke smell. |
#72
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I ask out of ignorance PS
Char Jackson wrote:
Why didn't the victims recognize the same thing? Because CO is colorless, odorless, and tasteless. I think you're confusing exhaust from your old furnace with CO. The exhaust most likely _contained_ a small amount of CO, but that's about it. The majority was smoke of some kind. CO won't have you coughing or smelling anything unusual. Humans can't see, smell, or taste CO. That's why CO detectors were developed. https://www.cdc.gov/co/faqs.htm What is Carbon Monoxide? Carbon monoxide, or “CO,” is an odorless, colorless gas that can kill you. Back in the 90's, a friend of mine was feeling sick in the evenings when she was home and fine during the day when she was at work. Likewise for her son - sick in the evenings and fine at school. After a few days of that, her furnace failed and she brought in a repairman. He discovered that the flue was plugged by a squirrel nest and the furnace exhaust had been venting into the basement. She and her son were lucky they were able to wake up each morning while that was going on. Neither of them smelled anything unusual. If she'd had a CO detector, I'm sure it would have gone nuts. You're assuming the failed-combustion process makes pure CO. It doesn't. The burned natural gas has a slight acidic quality to it. I don't know if some of the residue you see coating the inside of the furnace is due to burned mercaptans, or it's purely from the gas itself. (There can be white deposits, sometimes looking like filaments, inside the pipe or box.) The burning process is far from clean in any case. And this was an older furnace without forced air. I used to clean the burner head yearly with a vacuum cleaner, removing the white dust that fell down into it. That's why the thermocouple that senses ignition on my furnace failed. It got enough deposits (not white ones) on the outside, to impede thermal conductivity. And the furnace wasn't able to sense a flame. The service tech cleaned it up a bit, and I was surprised to find it never needed a second cleaning. The furnace went for years after that, until the fire box cracked and started to leak. The reading down at the fire box wall was 3ppm, and my CO detector with the LED readout was showing counts. (My CO detector wouldn't match the $1000 gadget the repair guy had.) My CO detector didn't alarm, because the level wasn't high enough. But I could both smell the problem, and cough in response. The smoke detector didn't go off (and there's no fog in the air either, it wasn't something you could see). The whole house smelled of the effluent, as the air handler had no problem circulating it uniformly all over the house. Just for the coughing, I needed to get it fixed. I think what we can conclude from this is: 1) My furnace was "burning clean". There was a lot of normal combustion product, and little CO. 2) Your friend had the exact opposite. The burning process wasn't working properly. The level of CO backing up in the house, was a lot higher. The question would be though, why wouldn't the combustion that was going on, cause you to cough ? One of the articles in this thread, states that if a modern furnace plugs up, it's not supposed to go over 400ppm CO. That's design intent. Only if the pressure regulator failed, or some goof ball cranked it wide open, would you achieve higher levels while the thing was (partially) blocked. A modern furnace won't run if completely blocked, because of the sensor for the ventor would trip. My experience with service people, is they tend to stay away from the gas valve. They don't fiddle with it. They'll drip their soap mixture on the fittings on either side to check for leaks, but generally are not interested in playing with it. My assumption was this was a liability issue. They will replace it, but, that's it. I suppose only a service tech in Denver, needs to adjust the thing (for altitude). Paul |
#73
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I ask out of ignorance PS
On Sun, 25 Nov 2018 15:55:19 +0100, Jesper Kaas
wrote: On Sun, 25 Nov 2018 12:24:15 +1300, Eric Stevens wrote: A very high level of CO is required to kill within minutes in which case the concentration is dangerously close to the lower explosive limit, 12.5% from memory. Here is a table showing the effect of different levels of CO: Concentration Symptoms 35 ppm (0.0035%) Headache and dizziness within six to eight hours of constant exposure 100 ppm (0.01%) Slight headache in two to three hours 200 ppm (0.02%) Slight headache within two to three hours; loss of judgment 400 ppm (0.04%) Frontal headache within one to two hours 800 ppm (0.08%) Dizziness, nausea, and convulsions within 45 min; insensible within 2 hours 1,600 ppm (0.16%) Headache, increased heart rate, dizziness, and nausea within 20 min; death in less than 2 hours 3,200 ppm (0.32%) Headache, dizziness and nausea in five to ten minutes. Death within 30 minutes. 6,400 ppm (0.64%) Headache and dizziness in one to two minutes. Convulsions, respiratory arrest, and death in less than 20 minutes. 12,800 ppm (1.28%) Unconsciousness after 2–3 breaths. Death in less than three minutes. So it takes only 1,28 %CO to kill in less than 3 minutes. The lower explosive limit is 12.5%. My mental gears must have jumped a cog with that 12,800 ppm you cited. Its been a long time since I worked with this. Maybe I was getting confused with the behaviour of CO when contaminated with hydrogen. -- Regards, Eric Stevens |
#74
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I ask out of ignorance
NY wrote:
I remember when I was working in a chemistry lab during my year off before university. One of the chemicals we used (I forget what it was) was the component that gives vomit its repulsive smell. We worked on it *only* in the fume cupboard. One day the Big Boss was bringing round an important guest, and he took the official party through our lab. One of my colleagues was slightly flustered to see all these important guests, and accidentally knocked over the little bottle of Essence of Puke. Despite the inward draught of the fume cupboard, enough of the vapour escaped to make a very noticeable pong. The Big Boss looked very concerned and whispered to my manager "Is everybody... er, OK. Or has someone just been... ill". Ah, I've just googled. Butyric acid is the stuff that make puke smell. They warn you about butyric acid in class. Of all the things to knock over. Paul |
#75
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I ask out of ignorance PS
On Sun, 25 Nov 2018 18:13:06 -0500, Paul wrote:
Char Jackson wrote: Why didn't the victims recognize the same thing? Because CO is colorless, odorless, and tasteless. I think you're confusing exhaust from your old furnace with CO. The exhaust most likely _contained_ a small amount of CO, but that's about it. The majority was smoke of some kind. CO won't have you coughing or smelling anything unusual. Humans can't see, smell, or taste CO. That's why CO detectors were developed. https://www.cdc.gov/co/faqs.htm What is Carbon Monoxide? Carbon monoxide, or “CO,” is an odorless, colorless gas that can kill you. Back in the 90's, a friend of mine was feeling sick in the evenings when she was home and fine during the day when she was at work. Likewise for her son - sick in the evenings and fine at school. After a few days of that, her furnace failed and she brought in a repairman. He discovered that the flue was plugged by a squirrel nest and the furnace exhaust had been venting into the basement. She and her son were lucky they were able to wake up each morning while that was going on. Neither of them smelled anything unusual. If she'd had a CO detector, I'm sure it would have gone nuts. You're assuming the failed-combustion process makes pure CO. That wasn't my assumption at all, and I said as much above. Here's what I said: I think you're confusing exhaust from your old furnace with CO. The exhaust most likely _contained_ a small amount of CO, but that's about it. The majority was smoke of some kind. CO won't have you coughing or smelling anything unusual. It doesn't. Actually, I was just pointing out that you weren't coughing from CO. |
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